Plants could be regarded as small chemical factories, which produce chemical substances via photosynthesis. If we can imitate photosynthesis in an artificial system, we can make clean fuels and materials out of sunlight and CO2. Huub de Groot is very close to designing a system of this kind.

The adsorption of D2 and CO2 on catalyst surfaces is studied using a molecular beam in ultra-high vacuum.

Despite the history of studies on methanol formation from CO2, the dominant elementary reaction steps that constitute the chemical mechanism for this catalyzed process are not determined.

Promotor: M.T.M. Koper, Co-Promotor: L.B.F. Juurlink

With the energy transition toward a renewable energy supply and a CO2-neutral economy, electrification of the energy system is rising in importance, which leads to the challenge of long-term storage of renewable electricity.

This thesis has shed light on some of the ways in which the local electrolyte composition can differ from the bulk and how these changes in the local reaction environment can determine the activity and/or selectivity of two important electrocatalytic reactions, namely, electrochemical CO2 reduction…

This thesis focuses on the synthesis, characterization and performance towards CO2 electroreduction of mono and bi-metallic particles based on p-block metals

The emissions of the Chinese industrial sector alone comprise 24.1% of global emissions (7.8 GtCyr−1 in 2015). This makes Chinese industrial emissions of unique national and international relevance in climate policy. This study reports a literature survey that quantitatively describes the evolution…

The goal of this thesis is to understand how interfacial parameters, such as the addition of organic additives, bulk pH or metal cations of the electrolyte, affect the relevant electrocatalytic reactions, i.e. electrochemical CO2 reduction reaction or hydrogen evolution reaction.

In eight chapters, the thesis of Rafaël Vos covers the effect of temperature and pressure on the electrochemical CO2 reduction.

Bicarbonate buffer is largely found in nature due to its ability to regulate pH variations around neutral values. As the pH changes, so does the speciation of the buffer.

The role of the interfacial environment during electrochemical reactions has been increasingly valued, especially for those reactions involving protons or hydroxyl ions.

This work describes several studies into the electroreduction of carbon dioxide (CO2RR), both regarding mechanistical aspects and catalyst stability considerations. Mechanistic insights into carbon-carbon bond formation on a silver catalyst are described in Ch 2, were we find an acetaldehyde-like surface…

M.T.M. Koper, Co-promotor: D.G.H. Hetterscheid

A discovery made in Leiden helps not only to make natural gas from CO2 but also to store renewable energy. Research by Professor Marc Koper and PhD student Jing Shen shows how this process can be implemented in a cost-effective and controllable way. Nature Communications, 2 september 2015.

Fearing a trade-off with economic growth, countries feel discouraged to cut their CO2 emissions. But do the two really not go together? Environmental scientist Ranran Wang and her colleagues investigated the relationship between economic growth and CO2 emissions in 73 countries from 1970 to 2016. Wang:…

Two students from the Leiden-Delft MSc Industrial Ecology programme have made a carbon footprint calculator for the website www.doemaarduurzaam.nl; the website where the Dutch public broadcasting organisations collect everything broadcasted about sustainability. The carbon footprint calculator allows…

Electrocatalysis allows for storing electricity or converting it into chemical bonds, producing chemical building blocks and fuels using renewable resources.

Yuvraj Birdja converted CO2 to formic acid to store energy in a sustainable way, with different catalysts. With this new knowledge, scientists are a step closer in industrially converting CO2 to chemicals and fuels. This can help reduce CO2 emission and the greenhouse effect.

In this thesis we have discussed several parameters that affect the electrochemical conversion of enviromentaly harmful molecules such as nitrates and carbon dioxide to more valuable and less deleterious compounds, in order to cast light onto the mechanism of the reaction to achieve an efficient and…

Promotor: H.J.A. Röttgering, Co-promotor: M. Haverkorn

A tax on CO2 emissions from products entering the EU offers unprecedented opportunities in the fight against global warming. That is the conclusion of research on which Leiden environmental scientist Hauke Ward collaborated. ‘A new world is opening up,’ Ward says. ‘But success hinges on how we involve…

Promotor: Prof.dr. H.W. Lenstra

How can we reduce CO2 emissions from industry? Leiden psychologists Emma Mors and Christine Boomsma are examining the public perception and acceptance around the capture and storage of carbon dioxide. This is part of the ALIGN CCUS European research programme.

The University's CO2 footprint has once again decreased. This is the conclusion of the 2022 Sustainability Report. The report also concludes that steps have been taken to integrate sustainability into Leiden University education and research.

Carbon dioxide capture and utilization technologies are necessary to create a truly circular economy. The electrochemical reduction of carbon dioxide to formate is an appealing carbon utilization method as it can be performed at room temperature and pressure, it only requires two electrons, and it has…

Promotor: H.W. Lenstra

In this thesis, we consider various (electro)chemical phenomena at surfaces and nanoparticles and their underlying atomistic processes, which we studied using first-principles methods such as density functional theory.

Promotor: K.E. Schalm, Co-promotor: S.S. Lee

Promotor: H.W. Lenstra, Jr., Co-promotor: B. de Smit

Bioenergy with carbon capture and storage (BECCS) is a promising method for removing carbon dioxide (CO2) from the atmosphere and simultaneously generating energy. Yet this method is controversial, as it may require a great deal of land and water. Researchers at Leiden University have now proposed a…

Artificial photosynthesis has recognised potential to produce green and sustainable fuels from earth-abundant resources such as water, carbon dioxide (CO2), and sunlight.

Fieldwork is a crucial part of the learning process for students in the Faculty of Archaeology. This includes both fieldwork aimed at collecting archaeological data and materials as well as fieldwork for heritage studies. The Faculty has established a specific centre of expertise to further shape these…

Promotor: V. Vitelli, Co-promotor: J. Paulose

The field and the classroom invites ethnographers to engage with critical and engaged pedagogies. Breaking down the barriers between fieldsite and lecture hall, this research cluster aims to interrogate the structures and values that shape anthropological and sociological education today.

Promotor: Prof.dr. A. Achucarro, Co-Promotor: J.W. van Holten

This thesis is about cosmological inflation and its relation to observations.

This dissertation focused on computational methods based on first principles calculations using the Density Functional Theory (DFT) framework. Emphasis was laid on affordable methods that can provide a tradeoff between computational expense and accuracy.

Artin L-functions associated to continuous representations of the absolute Galois group G_K of a global field K capture a lot of information about G_K as well as arithmetic properties of K.

Our cantilevers have a low intrinsic damping rate: this enables us to measure with low noise, since damping is proportionate to noise. However, when the magnet is close to the surface of a sample we want to study, we measure a much higher effective damping rate. This is caused by magnetic interaction…

Promotor: Prof.dr. P. Stevenhagen, Co-Promotor: Dr. J.H. Evertse

Promotor: Prof.dr.ir. T.H. Oosterkamp, N. de Jonge